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Holmium Oxide

2026-04-10

Introduction to Holmium Oxide

Holmium oxide, also known as holmium trioxide, is a compound composed of the rare earth element holmium and the oxygen element. Along with dysprosium oxide, it is one of the strongest known paramagnetic substances. Holmium oxide is one of the components of erbium oxide minerals. In its natural state, holmium oxide often coexists with trivalent oxides of lanthanide elements and requires specialized methods to separate it. Holmium oxide can be used to prepare special colored glasses. The visible absorption spectra of glasses and solutions containing holmium oxide exhibit a series of sharp peaks, making them traditionally used as calibration standards for spectrometers.

 

Holmium Oxide Properties

Appearance

Pale yellow or yellow powder, with a cubic crystal system of scandium oxide-type structure

Density (g/mL, 25℃)

8.16

Melting Point ( ℃)

2415

Boiling Point (℃, Atmospheric Pressure)

3900

Solubility

Insoluble in water, soluble in acids

 

Appearance properties:

Depending on lighting conditions, holmium oxide exhibits a remarkably distinct color variation. 

Under daylight illumination, it appears pale yellow; however, under illumination from primary-color light sources, it displays an intense orange-red hue—a color virtually indistinguishable from that of erbium oxide under identical lighting conditions—a phenomenon attributed to its sharp phosphorescent emission bands. 

Holmium oxide possesses a wide band gap of 5.3 eV and, as such, would theoretically be colorless. The yellow coloration of holmium oxide is instead caused by a high concentration of lattice defects (such as oxygen vacancies) and internal transitions within the Ho³⁺ ions.

 

Holmium Oxide Applications:

Holmium oxide is used to manufacture a new type of light source, the dysprosium holmium lamp, and can also be used as an additive for yttrium iron to obtain yttrium aluminum garnet and to produce metallic holmium.

Holmium oxide can be used as a yellow and red coloring agent for Soviet diamonds and glass.

 

Toxicological Data

On skin

Irritating to skin and mucous membranes

On eyes

Irritating to eyes

Sensitization Effects

No known sensitization phenomena

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