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What Are Anaerobic Adhesives?

2026-06-03

Anaerobic adhesives, commonly referred to as anaerobic glues, do not cure when exposed to oxygen or air. However, once isolated from the air, they rapidly polymerize and cure at room temperature—either on metal surfaces or in the presence of a catalyst—forming a strong bond and effective seal with the substrate.

Characteristics of Anaerobic Adhesives

① Anaerobic; 
② Most anaerobic adhesives are single-component, and their viscosity, strength, and initial cure time can be adjusted as needed; 
③ Excellent performance, with good weather resistance and resistance to various media; 
④ Minimal shrinkage during curing; nearly 100% of the components participate in the curing reaction, resulting in excellent sealing performance; 
⑤ Stable storage life, generally lasting more than one year; 
⑥ Versatile applications, suitable for locking, sealing, bonding, retaining, and filling.

Types of Anaerobic Adhesives

Based on their intended applications, anaerobic adhesives can be classified into thread-locking adhesives, pipe thread sealants, face sealants, cylindrical part retention adhesives, structural adhesives, and impregnation adhesives. Each type of anaerobic adhesive is formulated into different grades based on initial cure speed, viscosity, and cured mechanical properties and is distinguished by the use of different pigments.

Typical Formulations for Thread-Locking Anaerobic Adhesives

Typical Formulations for One-Component Thread-Locking Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Tetraethylene glycol dimethacrylate

62

Monomer, diester

Fumaric acid polyester

30

Modified resin, oligomer

Cumene hydroperoxide

3

Initiator

Aromatic amine accelerator

1

Accelerator to speed up curing reaction

Saccharin

2

Accelerator to speed up curing reaction

Fumed silica

2

Thixotropic agent, improves anti-sagging property of adhesive

Benzoquinone

0.01

Stabilizer, enhances storage stability of adhesive

Dyestuff

0.1

Colorant for tinting

Curing Performance

M10 bolt, fixture time: ~10–20 min at 25°C, breakaway torque: ~25–30 N·m

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Saccharin CAS 81-07-2
Hydrophobic Fumed Silica
Hydrophilic Fumed Silica
Ethoxylated bisphenol A diacrylate CAS 64401-02-1

Typical Formulations for Microencapsulated Thread-Locking Anaerobic Adhesives

Component A consists primarily of diacrylates, acrylic emulsion, accelerators, and polymerization inhibitors, while Component B consists of microcapsules containing dibenzoyl peroxide initiators coated with urea-formaldehyde resin.

Component

Ingredient

Parts by Mass

Function Description

Component A

Water

50

Dispersant, adjusts film thickness after coating

 

Sodium polyethylene-maleate solution

10

Adhesive with emulsification & dispersion

 

Ethoxylated bisphenol A dimethacrylate

35

performance

 

Oil-soluble red dye

0.2

Reactive monomer

 

Ground calcium carbonate

5

Colorant

 

Ferrocene

0.1

Filler for reinforcement

Component B

Microcapsules with benzoyl peroxide core & urea-formaldehyde resin shell

3.5

Catalyst

Curing Property

M10 bolt, fixture time ≈ 1 min at 25°C, breakaway torque = 15 N·m

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Initiator

Poly(ethylene glycol) dimethacrylate CAS 25852-47-5
Titanium dioxide CAS 13463-67-7
Polytetrafluoroethylene (PFA) CAS 9002-84-0
Ethylenediaminetetraacetic Acid(EDTA) CAS 60-00-4

Typical Formulations for Pipe Thread Sealing Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Polyethylene glycol dimethacrylate

20

Monomer, diester

Polyethylene glycol laurate

22

Resin, reduces bonding strength

Fumaric polyester

32

Modified oligomeric resin, increases adhesive viscosity

Cumene hydroperoxide

2

Initiator

Titanium dioxide

3

Pigment for coloration

Polytetrafluoroethylene powder

15

Filler, improves sealing property and chemical resistance

Saccharin

2

Accelerator to raise curing speed

Aromatic amine accelerator

1

Accelerator to accelerate curing reaction

Fumed silica

3

Thixotropic agent, prevents adhesive sagging

Benzoquinone

0.01

Stabilizer, improves adhesive storage stability

Curing Performance

M10 bolt, fixture time: 10~20 min at 25°C, breakaway torque: 1~5 N·m

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Typical Formulations for Retention-Type Anaerobic Adhesives

Analysis of Typical Formulations for Cylindrical Component Retention-Type Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Ethoxylated Bisphenol A Dimethacrylate

40

Monomer, diester

Hydroxypropyl Methacrylate

32

Monomer for improved bonding strength

Fumaric Polyester

20

Modified oligomeric resin

Cumene Hydroperoxide

.3

Initiator

Maleic Acid

1

Reinforcer to enhance bonding strength

Acetylphenylhydrazine

0.5

Accelerator to speed up curing reaction

Saccharin

0.5

Accelerator to increase curing rate

Aromatic Amine Accelerator

1

Accelerator to accelerate curing reaction

Fumed Silica

2

Thixotropic agent, prevents adhesive sagging

Benzoquinone

0.01

Stabilizer, improves storage stability of adhesive

Dyestuff

0.1

Colorant for tinting

Curing Performance

Fixture time: ~10–20 min at 25°C, compressive shear strength: ~20–25 MPa

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Typical Formulations for Structural Bonding Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Isobornyl Methacrylate

15

Diluent monomer, improves temperature resistance

Carbonate ether dihydroxydimethyl dimethacrylate

70

Diluent monomer, improves temperature resistance

Saccharin

1

Accelerator to increase curing speed

Acetylphenylhydrazine

0.3

Accelerator to speed up curing reaction

Benzoquinone

0.02

Stabilizer, improves adhesive storage stability

Tetrasodium EDTA

0.05

Metal ion chelating agent, enhances storage stability of adhesive

Cumene Hydroperoxide

1

Initiator

Curing Performance

Fixture time: 2~10 min at 25°C, tensile shear strength: 15 MPa (carbon steel substrate)

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Isobornyl Methacrylate CAS 7534-94-3
2-Hydroxypropyl Methacrylate CAS 27813-02-1
Ethylenediaminetetraacetic Acid(EDTA) CAS 60-00-4
Poly(ethylene glycol) dimethacrylate CAS 25852-47-5
Triethylene Glycol Dimethacrylate 109-16-0

Typical Formulations for Flat-Surface Sealing Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Polyethylene glycol dimethacrylate

15

Monomer, diester

Aminomethyl dimethacrylate

75

Polyurethane methacrylate diester, provides toughness and sealing performance

Cumene hydroperoxide

3.4

Initiator

Acetylphenylhydrazine

0.5

Accelerator to accelerate curing reaction

Saccharin

4

Accelerator to increase curing rate

Fumed silica

5

Thixotropic agent, prevents adhesive sagging

Benzoquinone

0.01

Stabilizer, improves adhesive storage stability

Dyestuff

0.1

Colorant for tinting

Curing Performance

Fixture time: 10–20 min at 25°C; breakaway torque of M10 bolt: 5–10 N·m

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Typical Formulations for Impregnation-Type Anaerobic Adhesives

Ingredient

Parts by Mass

Function Description

Triethylene glycol dimethacrylate

75

Monomer, diester

Lauryl methacrylate

15

Monomer

Hydroxypropyl methacrylate

5

Monomer

Surfactant

5

Improves the penetration of adhesive

Hydroquinone

0.05

Stabilizer, enhances adhesive storage stability

Azobisisobutyronitrile (AIBN)

0.5

Initiator

Diphosphate accelerator

0.1

Accelerator to speed up curing reaction

Dyestuff

0.01

Colorant for tinting

Curing Performance

Parts are pressure-impregnated in impregnation equipment and cured in hot water at 90°C. Max sealable pore diameter: 0.1~0.3 mm, maximum withstand pressure above 20 MPa

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